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LIVRES NUMÉRIQUES
Steric and Stereoelectronic Effects in Organic Chemistry - VEEJENDRA K. YADAV

Steric and Stereoelectronic Effects in Organic Chemistry

Titre de l'éditeur : Steric and Stereoelectronic Effects in Organic Chemistry

VEEJENDRA K. YADAV

 
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EN SAVOIR PLUS Résumé

The steric and stereoelectronic effects control the rate and stereochemical outcome of reactions. Hence, a decent understanding of the related concepts is essential for successful synthetic planning. The book attempts to address several important issues related to these concepts in a simplified manner, and is intended for graduate students. It lays stress on the important aspects of steric and stereoelectronic effects and their control on the conformational profile and reactivity features. The book covers the geometrical requirements for reactions at saturated and unsaturated carbons in both cyclic and acyclic systems, and the resultant stereochemical features. The aspect of geometrical flexibility is also covered with a few examples involving intramolecular reactions. It deals with the facial selectivity of nucleophilic additions to acyclic and cyclic carbonyl compounds, and explains how the steric and stereoelectronic effects control the same. The work comments on allylic strains and their stereochemical control on different reactions with the related conformational control. It is a must read to understand the control elements, the prominent among these elements are spiro-conjugation, periselectivity, torquoselectivity, a-effect, Hammett’s substituent constants, Hammond postulate, and Curtin-Hammett principle.


Détails
Prix : 153,22 $
Catégorie :
Auteur :  VEEJENDRA K. YADAV
Titre : Steric and Stereoelectronic Effects in Organic Chemistry
Date de parution : juin 2016
Éditeur : LIVRES NUMÉRIQUES DIVERS
Sujet : NUL DIVERS
ISBN : 9789811011399 (9811011397)
Référence Renaud-Bray : 3060252
No de produit : 3060252
Droits numériques
Format : EPUB
Disponibilité : Canada, consultez la liste des pays autorisés.
Gestion des droits numériques : Adobe DRM
Entrepôt numérique : NUMILOG
Nombre d'appareils autorisés : 3
Nombre de copier/coller : 0
Impression : 0

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Steric and Stereoelectronic Effects in Organic Chemistry , YADAV , VEEJENDRA K.
© LIVRES NUMÉRIQUES DIVERS 2016